资源类型

期刊论文 4

年份

2021 2

2018 1

关键词

检索范围：

排序： 展示方式：

Spontaneous polarization enhanced bismuth ferrate photoelectrode: fabrication and boosted photoelectrochemical water splitting property

《能源前沿（英文）》 2021年 第15卷 第3期   页码 781-790 doi: 10.1007/s11708-021-0782-8

摘要： In this paper, the fabrication of a highly orientated Bi2Fe4O9 (BFO) photoelectrode in the presence of two-dimensional (2D) graphene oxide (GO) was reported. It was found that the GO can be used as a template for controlling the growth of BFO, and the nanoplate composites of BFO/reduced graphene oxide (RGO) with a high orientation can be fabricated. The thickness of the nanoplates became thinner as the ratio of GO increased. As a result, the ferroelectric spontaneous polarization unit arranges itself in the space in a periodic manner, leading to the formation of a polarization field along a special direction. Therefore, the created built-in electric field of the nanoplate composites of BFO/RGO is improved upon the increase of the amount of RGO. As expected, carrier separation is enhanced by the built-in electric field, therefore substantially enhancing the photoelectrochemical (PEC) activity of water splitting compared to pure BFO under the irradiation of visible-light.

关键词： bismuth ferrate     ferroelectric polarisation     photoelectrochemical (PEC) water splitting     graphene oxide (GO)     high orientation    

HTML PDF 收藏

Surface modification by ligand growth strategy for dense copper bismuth film as photocathode to enhance hydrogen production activity

《能源前沿（英文）》 doi: 10.1007/s11708-023-0893-5

摘要： Hydrogen production from photoelectrochemical (PEC) water splitting has been regarded as a promising way to utilize renewable and endless solar energy. However, semiconductor film grown on photoelectrode suffers from numerous challenges, leading to the poor PEC performance. Herein, a straightforward sol-gel method with the ligand-induced growth strategy was employed to obtain dense and homogeneous copper bismuthate photocathodes for PEC hydrogen evolution reaction. By various characterizations, it was found that the nucleation and surface growth of CuBi2O4 layer induced by 2-methoxyethanol ligand (2-CuBi2O4) demonstrated a decent crystallinity and coverage, as well as a large grain size and a low oxygen vacancy concentration, leading to the good ability of light absorption and carrier migration. Consequently, under simulated sunlight irradiation (AM1.5G, 100 mW/cm2), the 2-CuBi2O4 photocathode achieved an enhanced photocurrent density of −1.34 mA·cm−2 at 0.4 V versus the reversible hydrogen electrode and a promising applied bias photon-to-current efficiency of 0.586%. This surface modification by ligand growth strategy will shed light on the future design of advanced photoelectrodes for PEC water splitting.

关键词： copper bismuthate     photocathode     ligand growth strategy     dense film     PEC    

HTML PDF 收藏

Photoelectrocatalytic generation of H and S from toxic HS by using a novel BiOI/WO nanoflake array photoanode

《能源前沿（英文）》 2021年 第15卷 第3期   页码 744-751 doi: 10.1007/s11708-021-0775-7

摘要： In this paper, a photoelectrocatalytic (PEC) recovery of toxic H2S into H2 and S system was proposed using a novel bismuth oxyiodide (BiOI)/ tungsten trioxide (WO3) nano-flake arrays (NFA) photoanode. The BiOI/WO3 NFA with a vertically aligned nanostructure were uniformly prepared on the conductive substrate via transformation of tungstate following an impregnating hydroxylation of BiI3. Compared to pure WO3 NFA, the BiOI/WO3 NFA promotes a significant increase of photocurrent by 200%. Owing to the excellent stability and photoactivity of the BiOI/WO3 NFA photoanode and I–/I 3− catalytic system, the PEC system toward splitting of H2S totally converted S2– into S without any polysulfide ( Sx n−) under solar-light irradiation. Moreover, H2 was simultaneously generated at a rate of about 0.867 mL/(h·cm). The proposed PEC H2S splitting system provides an efficient and sustainable route to recover H2 and S.

关键词： bismuth oxyiodide (BiOI)/ tungsten trioxide (WO3) nano-flake arrays (NFA)     photoelectrocatalytic (PEC)     H2S splitting     H2     S    

HTML PDF 收藏

Layered double hydroxide-based core-shell nanoarrays for efficient electrochemical water splitting

Wenfu Xie, Zhenhua Li, Mingfei Shao, Min Wei

《化学科学与工程前沿（英文）》 2018年 第12卷 第3期   页码 537-554 doi: 10.1007/s11705-018-1719-6

摘要：

Electrochemical water splitting is an efficient and clean strategy to produce sustainable energy productions (especially hydrogen) from earth-abundant water. Recently, layered double hydroxide (LDH)-based materials have gained increasing attentions as promising electrocatalysts for water splitting. Designing LDHs into hierarchical architectures (e.g., core-shell nanoarrays) is one of the most promising strategies to improve their electrocatalytic performances, owing to the abundant exposure of active sites. This review mainly focuses on recent progress on the synthesis of hierarchical LDH-based core-shell nanoarrays as high performance electrocatalysts for electrochemical water splitting. By classifying different nanostructured materials combined with LDHs, a number of LDH-based core-shell nanoarrays have been developed and their synthesis strategies, structural characters and electrochemical performances are rationally described. Moreover, further developments and challenges in developing promising electrocatalysts based on hierarchical nanostructured LDHs are covered from the viewpoint of fundamental research and practical applications.

关键词： layered double hydroxides (LDHs)     core-shell nanoarrays     oxygen evolution reaction (OER)     hydrogen evolution reaction (HER)     photoelectrochemical water splitting (PEC)    

HTML PDF 收藏

标题 作者 时间 类型 操作

Spontaneous polarization enhanced bismuth ferrate photoelectrode: fabrication and boosted photoelectrochemical water splitting property

期刊论文

Surface modification by ligand growth strategy for dense copper bismuth film as photocathode to enhance hydrogen production activity

期刊论文

Photoelectrocatalytic generation of H and S from toxic HS by using a novel BiOI/WO nanoflake array photoanode

期刊论文

Layered double hydroxide-based core-shell nanoarrays for efficient electrochemical water splitting

Wenfu Xie, Zhenhua Li, Mingfei Shao, Min Wei

期刊论文